Novel hypervalent Se+4 and Te+4 reagents and their use in synthesis


Ph2SeF2, PhSeF3, PhTeF5,

Main co-workers:

Dr. S. A. Lermontov, Dr. A. G. Kutateladze.


  1. Lermontov S. A., Zavorin S. I., Bakhtin I. V., Pushin A. N., Zefirov N. S., Stang P. J., Fluorination of olefins with PhSeF3, PhSeF5 and PhTeF5. Journal of Fluorine Chemistry, 1998, 87, (1), 75-83.
  2. Lermontov S. A., Shkavrov S. V., Lermontov A. S., Zavelsky V. O., Zefirov N. S., Oxidative fluorination of some organoantimony and organotellurium compounds by 2-hydroperfluoropropyl azide. Journal of Fluorine Chemistry, 1999, 94, (1), 43-45.
  3. Lermontov S. A., Rakov I. M., Zefirov N. S., Stang P. J., Triphenylbismuth difluoride - a novel reagent for the oxidative fluorination of P(III), Se(II), and Sb(III) compounds. Phosphorus, Sulfur and Silicon and the Related Elements, 1994, 92, (1-4), 225-229.
  4. Kutateladze A. G., Kice J. L., Kutateladze T. G., Zefirov N. S., A one-pot trifunctionalization of olefins with benzeneseleninic and trifluoroacetic anhydrides using a commonly undesirable side reaction as a key step. Journal of Organic Chemistry, 1993, 58, (5), 995-996.

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