Novel hypervalent Xe+2 reagents and their use in synthesis



Main co-workers:

Prof. V. V. Zhdankin, Dr. V. K. Brel, Prof. P. Stang.


  1. Brel V. K., Zefirov N. S., Hypervalent compounds of xenon. Chapter 13 in "Chemistry of hypervalent compounds", Kin-ya Akiba, Ed., 1999, Wiley-VCH, New York, 389-408.
  2. Kasumov T. M., Brel V. K., Koz'min A. S., Zefirov N. S., Potekhin K. A., Stang P. J., Xenone fluoride triflate as a new oxidant for the generation of aryliodozo derivatives as key intermediated in the synthesis of diaryliodonium salts. New Journal of Chemistry, 1997, 21, (12), 1347-1351.
  3. Zhdankin V. V., Stang P. J., Zefirov N. S., Preparation, spectral identification and chemical reaction af alkynyl xenonium tetrafluoroborates, R-Cbond-3C-Xe+ BF4-: novel organoxenonium species. Chemical Communications, 1992, 7, 578-579.
  4. Zefirov N. S., Gakh A. A., Zhdankin V. V., Stang P. J., Interaction of fluoroxenonium triflate, fluorosulfate and nitrate with alkenes. Stereochemical evidence for the electrophilic noble gas cation addition to the carbon-carbon double bond. Journal of Organic Chemistry, 1991, 56, (4), 1416-1418.

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