ENG KOI WIN

Novel hypervalent I+3 reagents and their use in synthesis

I+3 reagents:

I+3

Examples of reactions:

Reaction

Main co-workers:

Dr. A. S. Koz'min, Prof. P. Stang, Prof. V. V. Zhdankin.

Literature:

  1. Brel V. K., Zefirov N. S., Hypervalent compounds of xenon. Chapter 13 in "Chemistry of hypervalent compounds", Kin-ya Akiba, Ed., 1999, Wiley-VCH, New York, 389-408.
  2. Zefirov N. S., Novel reagents of iodine(+III) and sulfur. Pure and Applied Chemistry, 1996, 68, (4), 881-890.
  3. Zhdankin V. V., Tykwinski R., Berglund B., Mullikin M., Caple R., Zefirov N. S., Koz'min A. S., Iodosobenzene tetrafluoroborate, hexafluoroantimonate, and hexafluorophosphate: stable electrophilic hypervalent iodine reagents without nucleophilic ligands. Journal of Organic Chemistry, 1989, 54, (11), 2609-2612.
  4. Zhdankin V. V., Mullikin M., Tykwinski R., Berglund B., Caple R., Zefirov N. S., Koz'min A. S., Carbon-carbon bond formation in reaction of PhIO·HBF4/silyl enol ether adduct with alkenes or silyl enol ethers. Journal of Organic Chemistry, 1989, 54, (11), 2605-2608.


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