ENG KOI WIN

Novel reactions and reagents

Examples of novel reagents:

RSeF, RSeF3,
RTeF3, PhIF2,
FXeOSO3F,
CF3CHFCF2N3,
ClOSO2Cl,
R2NSO2OCl,
O=IOSO2R,
NC-I+-CN·TfO-,
O(IPh-OTf)2
ONOSO2OR.

Literature:

  1. Zefirov N. S., Novel reagents of iodine(+III) and sulfur. Pure and Applied Chemistry, 1996, 68, (4), 881-890.
  2. Lermontov S. A., Shkavrov S. V., Lermontov A. S., Zavelsky V. O., Zefirov N. S., Oxidative fluorination of some organoantimony and organotellurium compounds by 2-hydroperfluoropropyl azide. Journal of Fluorine Chemistry, 1999, 94, (1), 43-45.
  3. Pirguliyev N. Sh., Kasumov T. M., Brel V. K., Zefirov N. S., Stang P. J., Xenon fluorosulfate: an efficient reagent for synthesis of (p-phenylene)-bis-iodonium salts. Synthesis, 1999, 1297-1299.
  4. Zyk N. V., Nesterov E. E., Khlobystov A. N., Zefirov N. S., Barnhurst L. A., Kutateladze A. G., Reactions of nitrosonium ethyl sulfate with olefins and dienes: an experimental and theoretical study. Journal of Organic Chemistry, 1999, 64, 7121-7128.
  5. Lermontov S. A., Zavorin S. I., Bakhtin I. V., Pushin A. N., Zefirov N. S., Stang P. J., Fluorination of olefins with PhSeF3, PhSeF5 and PhTeF5. Journal of Fluorine Chemistry, 1998, 87, (1), 75-83.
  6. Matveeva E. D., Podrugina T. A., Zefirov N. S., 2,4,4,6-Tetrabromocyclohexa-2,5-dienone in the presence of triphenylphosphine as a regiospecific and stereoselective reagent for the nucleophilic substitution of bromine for hydroxyl. Mendeleev Communications, 1998, (1), 21-22.


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