The problem of conformational effects

Examples of conformational equilibria:


Main co-workers:

Dr. V. V. Samoshin, Dr. V. A. Palyulin, Dr. I. G. Mursakulov.


  1. Zefirov N. S., The problem of conformational effects. Tetrahedron, 1977, 33, (24), 3193-3202.
  2. Zefirov N. S., On electronic and conformational effects in six-membered rings. Tetrahedron Letters, 1975, 13, 1087-1090.
  3. Zefirov N. S., Samoshin V. V., Subbotin O. A., Baranenkov V. I., Wolfe S., The gauche effect. On the nature of the interaction between electronegative substituents in trans-1,2-dicybstituted cyclohaxanes. Tetrahedron, 1978, 34, 2953-2959.
  4. Zefirov N. S., Palyulin V. A., Conformational analysis of bicyclo[3.3.1]nonanes and their hetero analogs in "Topics in Stereochemistry", Eliel E. L., Wilen S. H. Eds., John Wiley & Sons, Inc., 1991, 20, NY, 171-230.
  5. Zefirov N. S., Chalenko E. G., Aripovsky A. V., Mursakulov I. G., Guseinov M. M., Ramazanov E. A., New conformational effect: predominance of the axial conformation in spiro[5,2]octan-4-ol derivatives. Chemical Communications, 1978, 3, 147-148.
  6. Zefirov N. S., Stereochemical studies. General equation of relationship between products ratio and conformational equilibrium. Tetrahedron, 1977, 33, 2719-2722.
  7. Vatsadze S. Z., Krut'ko D. P., Zyk N. V., Zefirov N. S., Churakov A. V., Howard J. A., First 1H NMR observation of chair-boat conformers in bispidinone system. Molecular structure of 3,7-diisopropyl-1,5-diphenyl-3,7-diazabicyclo[3.3.1]hohane-9-one. Mendeleev Communications, 1999, 103-105.
  8. Zefirov N. S., Gurvich L. G., Stereochemical studies. On the specific directing effect in the mercuration of olefins. Stereochemistry of the methoxymercuration of 1-cyano-3-cyclohexene and trans-1,2-dicyano-4-cyclohexene. Journal of Organometallic Chemistry, 1974, 81, 309-320.
  9. Mursakulov I. G., Ramazanov E. A., Guseinov M. M., Zefirov N. S., Samoshin V. V., Eliel E. L., Stereochemical stuies. Conformational equilibria of 2-substituted 1,1-dialkylcyclohexanes. Tetrahedron, 1980, 36, 1885-1890.

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